Evaluation of In Situ Heterogeneity of Elements in Solids: Implications for Analytical Geochemistry     

Michael H. Ramsey  Grace Solomon‐Wisdom  Ariadne Argyraki 《Geostandards and Geoanalytical Research》2013,37(4):379-391

A general method for the evaluation of in situ heterogeneity of geochemical materials is described and the significance of the results discussed, by using three case studies and earlier data sets. The heterogeneity of Pb in soil (expressed as RSD due to sampling, RSD_samp) varies from < 5 to > 100% between different sites, in a way that relates to the mode of deposition of the element. The heterogeneity of an element also varies systematically as a function of the distance scale at some sites. This variation can be modelled using linear regression, accounting for over 90% of the experimental variance, at seven scales over three orders of magnitude. Variation in heterogeneity between elements at the same site, seems to be somewhat diagnostic of the origin of the element, lithogenic being less than anthropogenic, although the later is also being modified by the mode of deposition. Where the heterogeneity is large (RSD > 30%), it is proposed that it can be expressed more accurately as a heterogeneity factor (10^GSDsamp), to reflect its frequency distribution, which is positively skewed towards higher concentration values.  相似文献   

Miniaturization of the flowing fluid electric conductivity logging technique     

Su GW  Quinn NW  Cook PJ  Shipp W 《Ground water》2006,44(5):754-757

An understanding of the hydraulic properties of the aquifer and the depth distribution of salts is critical for evaluating the potential of ground water for conjunctive water use and for maintaining suitable ground water quality in agricultural regions where ground water is used extensively for irrigation and drinking water. The electrical conductivity profiles recorded in a well using the flowing fluid electric conductivity (FEC) logging method can be analyzed to estimate interval-specific hydraulic conductivity and estimates of the salinity concentration with depth. However, operating irrigation wells commonly allow limited access, and the traditional equipment used for FEC logging cannot fit through the small access pipe intersecting the well. A modified, miniaturized FEC logging technique was developed for use in wells with limited access. In addition, a new method for injecting water over the entire screened interval of the well reduces the time required to perform FEC logging.  相似文献   

Interpreting velocities from heat-based flow sensors by numerical simulation   总被引：1，自引：0，他引：1  

Su GW  Freifeld BM  Oldenburg CM  Jordan PD  Daley PF 《Ground water》2006,44(3):386-393

We have carried out numerical simulations of three-dimensional nonisothermal flow around an in situ heat-based flow sensor to investigate how formation heterogeneities can affect the interpretation of ground water flow velocities from this instrument. The flow sensor operates by constant heating of a 0.75-m-long, 5-cm-diameter cylindrical probe, which contains 30 thermistors in contact with the formation. The temperature evolution at each thermistor can be inverted to obtain an estimate of the ground water flow velocity vector using the standard interpretive method, which assumes that the formation is homogeneous. Analysis of data from heat-based flow sensors installed in a sand aquifer at the Former Fort Ord Army Base near Monterey, California, suggested an unexpected component of downward flow. The magnitudes of the vertical velocities were expected to be much less than those of the horizontal velocities at this site because the sensors were installed just above a clay aquitard. Numerical simulations were conducted to examine how differences in thermal conductivities may lead to spurious indications of vertical flow velocities. We found that a decrease in the thermal conductivity near the bottom of the sensor can perturb the temperature profiles along the instrument in such a manner that analyses assuming homogeneous thermal conductivity could indicate a vertical flow component even though flow is actually horizontal. This work demonstrates how modeling can be used to simulate instrument response to formation heterogeneity and shows that caution must be used in interpreting data from such devices.  相似文献   

Responding to flood risk in Louisiana: the roles of place attachment,emotions, and location     

Holley  Jason R.  McComas  Katherine A.  Lambert  Catherine E.  Snider  Natalie P.  Tucker  Grace K. 《Natural Hazards》2022,113(1):615-640

Natural Hazards - Drawing from protection motivation theory (PMT), we examined how place attachment and negative emotions, alongside threat and coping appraisals, personal experiences, and...  相似文献   

Controls on salt marsh accretion: A test in salt marshes of Eastern Canada     

Gail?L.?ChmuraEmail author  Grace?A.?Hung 《Estuaries and Coasts》2004,27(1):70-81

We used¹³⁷Cs-dating to determine vertical accretion rates of 15 salt marshes on the Bay of Fundy, the Gulf of St. Lawrence, and the Atlantic coast of Nova Scotia. Accretion rates are compared to a number of factors assumed to influence vertical marsh accretion: rates of relative sea-level rise, climatic parameters (average daily temperatures and degree days) and latitude (related to insolation and day length), sediment characteristics (organic matter inventory, bulk, mineral, and organic matter density), distance of the core site from the nearest source of tidal waters, and the tidal range. Uniques to our study is a consideration of climatic parameters and latitude, which should influence organic matter production, and thus vertical accretion rates. Significant predictors of accretion rates (in order of importance) were found to be organic matter inventory, distance from a creek, and range of mean tides. Contrary to conclusions from previous studies, we found that accretion rates decreased with increasing tidal range, probably because we considered a wider span of tidal ranges, from micro- to macrotidal. Although four marshes with low organic matter inventories also show a deficit in accretion with respect to relative sea-level rise, organic matter is not limiting in two-thirds of the marshes studied, despite shorter growing seasons.  相似文献   

Biogeomorphic controls on sedimentation and substrate on a vegetated tidal freshwater delta in upper Chesapeake Bay     

Gregory B. Pasternack  Grace S. Brush 《Geomorphology》2002,43(3-4)

Classic geomorphic theory on the dynamics of delta evolution posits a purely physical mechanism for spatial and temporal patterns of sediment accumulation over decades to centuries. Meanwhile, intertidal marsh vegetation that grows on deltas is well known to influence short-term fluid mechanics and sediment transport. This dichotomy points toward a large gap in the understanding of the role of vegetation in delta evolution as a function of spatial and temporal scale. In the research reported here, substrate characteristics and seasonal sedimentation rates in a tidal freshwater delta at the head of a Chesapeake Bay tributary were studied to assess the existence and extent of physical–ecological interactions on a delta over the seasonal to interannual time scale. Both vegetation data and sediment variables showed significant spatial variations at this time scale. When multiple regression analysis was used to compare vegetated versus nonvegetated conditions on the studied delta, 84% of the spatial variation in sedimentation with vegetation was explained by plant association and distance to the nearest distributary channel. In contrast, only 33% of the spatial variation in sedimentation could be explained when no vegetation was present, and in that case, the dominant variable was distance to the subtidal front. Spatial variability in organic content was less sensitive to vegetation and strongly influenced by the distance to the subtidal front. Substrate grain size parameters were explained by distance to the subtidal front and to the nearest distributary channel. This research demonstrates that sediment sequestration, and thus delta evolution, is highly predictable at the habitat scale and is driven by a strong interplay between abiotic and biotic variables.  相似文献   

A 2,500-year history of anoxia and eutrophication in Chesapeake Bay   总被引：2，自引：0，他引：2  

Sherri Rumer Cooper  Grace S. Brush 《Estuaries and Coasts》1993,16(3):617-626

Ongoing monitoring programs and historical data are not sufficient to establish anthropogenic effects on the ecology of Chesapeake Bay. However, stratigraphic records preserved in the sediments can be used to reconstruct both prehistoric and historic sedimentation and water conditions of the bay, including anoxia and eutrophication. Pollen, diatoms, total organic carbon (TOC), nitrogen, total sulfur, and an estimate of the degree of pyritization of iron (DOP) are being used as paleoecological indicators in dated sediment cores for the purpose of reconstructing a long-term environmental history of the bay. Analysis of the data indicates that sedimentation rates, anoxic conditions, and eutrophication have increased in the Chesapeake Bay since the time of European settlement. For example, since initial land clearance around 1760, sedimentation rates have increased from as low as 0.02 cm yr^?1 to an average 0.22 cm yr^?1, and TOC from 0.14 mg cm^?2 yr^?1 to a high 4.96 mg cm^?2 yr^?1. Diatom community structure shows a steady decrease in overall diversity since 1760 and the centric:pennate ratio has increased significantly since 1940.  相似文献   

Public health in the Canadian Arctic: contributions from International Polar Year research     

Sandra Owens  Philippe De Wals  Grace Egeland  Christopher Furgal  Yang Mao  Gerald Y. Minuk  Paul A. Peters  Manon Simard  éric Dewailly 《Climatic change》2012,115(1):259-281

The contributions of several IPY health projects are highlighted in the context of population health indicators for Inuit Nunangat. Food and housing are two critical social determinants of health contributing to health issues on many levels. The nutritional deficit associated with food insecurity and the transition away from traditional and towards market foods represents a dual risk with profound consequences. Knowledge of the physiological benefits associated with traditional food consumption is increasing, including for mental health and chronic disease. Ensuring the safety of traditional foods in terms of zoonotic diseases is thus highly valuable and efforts to institute adequate monitoring and address knowledge gaps are underway. Acute respiratory disease among the young remains a significant public health issue with potential long term effects. The human papilloma virus is manifesting itself among women across northern Canada with high risk types that are more similar to profiles observed in Europe than in North America with possible implications for immunization programs. Despite a high prevalence of Hepatitis B virus infections among residents of Inuit Nunangat, the outcomes appear to be relatively benign. Communication of new knowledge on the manifestation of this virus among northern populations is provided to health care providers in the North through modern technology.  相似文献   

Historical Land Use,Nitrogen, and Coastal Eutrophication: A Paleoecological Perspective     

Grace S. Brush 《Estuaries and Coasts》2009,32(1):18-28

Organisms and chemicals preserved in sediment cores from the Chesapeake estuary in mid-Atlantic USA are consistent with a precolonial landscape covered with a diversity of forests and marshes, large and small. During the past 300 years, many of the wetlands have been drained, and the landscape was converted to agricultural fields and urban and suburban development. During this time, sources of nitrogen have diversified, and loadings have increased. Since precolonial time, the mesohaline estuary has become increasingly eutrophic and anoxic. Estuaries and coastal regions throughout the world have experienced similar conditions in their recent history. These changes are recorded in Chesapeake sediment cores by increases in ragweed pollen, dry taxa, sedimentation rates, nitrogen influxes, and a major change in estuarine autotrophs from benthic to planktonic. In many areas, attempts to reverse estuarine eutrophication and anoxia have centered on restoring streams and riparian areas and reducing fertilizer use on agricultural lands. However, data from soils and historical reports and the paleoecological record suggest that to reduce the effects of modern nitrogen inputs, it may be necessary to locate and enhance denitrifying areas throughout the watershed.  相似文献   

The effect of submerged plateaux on Pleistocene gyral circulation and sea-surface temperatures in the Southwest Pacific     

Bruce W. Hayward  George H. Scott  Martin P. Crundwell  James P. Kennett  Lionel Carter  Helen L. Neil  Ashwaq T. Sabaa  Kate Wilson  J. Stuart Rodger  Grace Schaefer  Hugh R. Grenfell  Qianyu Li 《Global and Planetary Change》2008,63(4):309-316

Uniquely in the Southern Hemisphere the New Zealand micro-continent spans the interface between a subtropical gyre and the Subantarctic Circumpolar Current. Its 20° latitudinal extent includes a complex of submerged plateaux, ridges, saddles and basins which, in the present interglacial, are partial barriers to circulation and steer the Subtropical (STF) and Subantarctic (SAF) fronts. This configuration offers a singular opportunity to assess the influence of bottom topography on oceanic circulation through Pleistocene glacial – interglacial (G/I) cycles, its effect on the location and strength of the fronts, and its ability to generate significant differences in mixed layer thermal history over short distances.For this study we use new planktic foraminiferal based sea-surface temperature (SST) estimates spanning the past 1 million years from a latitudinal transect of four deep ocean drilling sites. We conclude that: 1. the effect of the New Zealand landmass was to deflect the water masses south around the bathymetric impediments; 2. the effect of a shallow submerged ridge on the down-current side (Chatham Rise), was to dynamically trap the STF along its crest, in stark contrast to the usual glacial–interglacial (G–I) meridional migration that occurs in the open ocean; 3. the effect of more deeply submerged, downstream plateaux (Campbell, Bounty) was to dynamically trap the SAF along its steep southeastern margin; 4. the effects of saddles across the submarine plateaux was to facilitate the development of jets of subtropical and subantarctic surface water through the fronts, forming localized downstream gyres or eddies during different phases in the G–I climate cycles; 5. the deep Pukaki Saddle across the Campbell-Bounty Plateaux guided a branch of the SAF to flow northwards during each glacial, to form a strong gyre of circumpolar surface water in the Bounty Trough, especially during the mid-Pleistocene Climate Transition (MIS 22-16) when exceptionally high SST gradients existed across the STF; 6. the shallower Mernoo Saddle, at the western end of the Chatham Rise, provided a conduit for subtropical water to jet southwards across the STF in the warmest interglacial peaks (MIS 11, 5.5) and for subantarctic water to flow northwards during glacials; 7. although subtropical or subantarctic drivers can prevail at a particular phase of a G–I cycles, it appears that the Antarctic Circumpolar Current is the main influence on the regional hydrography.Thus complex submarine topography can affect distinct differences in the climate records over short distances with implications for using such records in interpreting global or regional trends. Conversely, the local topography can amplify the paleoclimate record in different ways in different places, thus enhancing its value for the study of more minor paleoceanographic influences that elsewhere are more difficult to detect. Such sites include DSDP 594, which like some other Southern Ocean sites, has the typical late Pleistocene asymmetrical saw-tooth G–I climate pattern transformed to a gap-tooth pattern of quasi-symmetrical interglacial spikes that interrupt extended periods of minimum glacial temperatures.  相似文献